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Schwarzenbach - Environmental organic chemistry

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Schwarzenbach Environmental organic chemistry
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    Environmental organic chemistry
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Appendix A
Mathematics
  1. A.1 The Normal Distribution
  2. A.2 The Error Function
1.1 The Normal Distribution

The one-dimensional normal (or Gaussian) distribution along the x-axis is defined by:

(17-3) where is the standard deviation and 2 is the variance of the distribution px - photo 1

where is the standard deviation and 2 is the variance of the distribution. p(x) has the following properties:

(1) 2 3 Integrals within finite boundaries have the following values 4 - photo 2
(2) 3 Integrals within finite boundaries have the following values 4 5 - photo 3
(3) Integrals within finite boundaries have the following values 4 5 - photo 4

Integrals within finite boundaries have the following values:

(4) 5 Figure A1 The normal distribution where each band on the x-axis has a - photo 5
(5) Figure A1 The normal distribution where each band on the x-axis has a width of - photo 6
Figure A1 The normal distribution where each band on the x-axis has a width of - photo 7

Figure A.1 The normal distribution where each band on the x-axis has a width of one standard deviation ().

1.2 The Error Function

The Error Function erf(y) along the y-axis is defined by:

(1) The Complementary Error Function is 2 Symmetry properties and integral - photo 8

The Complementary Error Function is:

(2) Symmetry properties and integral 3 4 Special values y erfy - photo 9

Symmetry properties and integral:

(3) 4 Special values y erfy erfcy 048 05 05 - photo 10
(4) Special values y erfy erfcy 048 05 05 05 - photo 11

Special values:

yerf(y)erfc(y)
0.480.50.5
0.50.5210.479
0.8420.158
0.9950.005
Figure A2 a The Error Function erfy for y 3 to y 3 b One-sided - photo 12

Figure A.2 (a) The Error Function erf(y) for y = 3 to y = + 3. (b) One-sided diffusion from a boundary at y = 0 (Eq. 17-9) is given by the Complementary Error Function erfc(y) for y > 0.

Table A.1 The Error Function and its Complement

Only available online at the book's companion website.
Appendix B
Physical Constants and Units
  1. B.1 Some Useful Constants (IUPAC)
  2. B.2 Dimension and Units of Physical Quantities
  3. B.3 Specific Properties of Water at 20C
  4. B.4 Specific Properties of Dry Air
B.1 Some Useful Constants (IUPAC)
Atomic massmu1.66054021027 kg
Avogadro's numberNA6.02213671023 mol1
Boltzmann's constantk1.3806581023 J K1
Elementary chargee1.602177331019 C
Faraday's constantF9.6485309104 C mol1
Gas (molar) constantR= k N = 8.314510 J mol1K1
0.083145 L bar mol1K1
Gravitational accelerationg= 9.80665 m s2
Molar volume of an ideal gas at 1 bar and 25CPicture 13= 24.465 L mol1
Permittivity of vacuumo8.8541871012 C V1m1
Planck's constanth6.62607551034 J s
Zero of Celsius scale0C= 273.15 K
B.2 Dimension and Units of Physical Quantities

Dimensions are: M = mass; L = length; T = time; I = current

Physical QuantityName of UnitSymbolDimensionsSI Units
Amount of photonseinsteineinsteinmol photons
ConcentrationmolarMML3103 mol m3
Dipole momentdebyeDLTI3.341030 C m
Electric chargecoulombCTIA s
Electric potentialvoltVML2T3I1J C1 = kg m2 s3A1
EnergyjouleJN m = kg m2 s2
volt-coulombVCJ
watt-secondWsJ
ergergML2T2107 J
liter-atmopshereL atm101.325 J
caloriecal4.184 J
electron-volteV1.601019 J
ForcenewtonNMLT2kg m s2
dynedyn105 N
FrequencyhertzHzT1s1
Physical QuantityName of UnitSymbolDimensionsSI Units
Lengthangstrom1010 m
nanometernm109 m
micrometerm106 m
millimetermmL103 m
centimetercm102 m
kilometerkm103 m
Masston (metric)tM103 kg
PressurepascalPaN m2 = kg m1 s2
barbar105 Pa
atmosphereatm101,325 Pa
torrtorrML1T2133.32 Pa
millimeter mercurymm Hg133.32 Pa
pounds per square inchpsi6.89103 Pa
Timeminutemin60 s
hourhT3,600 s
dayd86,400 s
year (365.25 d)yr31,557,600 s
Dynamic viscositycentipoisecpML1T1103 kg m1s1
VolumeliterL103 m3
millilitermLL3106 m3
microliterL109 m3
B.3 Specific Properties of Water at 20C
Densityw998.205kg m3
Thermal expansivity20678106 K1 Dynamic viscosity w 1002103 kg m1s1 Kinematic - photo 14
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