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This handbook sets out to bridge the technological gap between scientific literature and industrial practices. It examines the complex and advanced technology of adhesives, presenting useful new information for many important classes of adhesives, and discusses all aspects of adhesive bonding.
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A. Pizzi University of the Witwatersrand Johannesburg, South Africa
K. L. Mittal Skill Dynamics, an IBM Company Thornwood, New York
MARCEL DEKKER, INC. NEW YORK BASEL
Page ii
Library of Congress Cataloging-in-Publication Data
Handbook of adhesive technology / edited by A. Pizzi, K. L. Mittal. p. cm. Includes bibliographical references and index. ISBN 0-8247-8974-1 (alk. paper) 1. Adhesives. I. Pizzi, A. (Antonio). II. Mittal, K. L. TP968.H347 1994 668'.3--dc20 944800 CIP
The publisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketing at the address below.
This book is printed on acid-free paper.
Copyright 1994 by Marcel Dekker, Inc. All Rights Reserved.
Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfilming, and recording, or by any information storage and retrieval system, without permission in writing from the publisher.
Marcel Dekker, Inc. 270 Madison Avenue, New York, New York 10016
Current printing (last digit): 10 9 8 7 6 5 4 3
PRINTED IN THE UNITED STATES OF AMERICA
Page iii
PREFACE
Bonding different materials together by means of an adhesive may appear to most people as a mundane occurrence. In reality a great deal of technology backs the apparently simple action of bonding. Thus, a complex and advanced technology, or series of technologies, has arisen to deal with adhesives and their applications in many fields. The diversity of substrates and the continuous introduction of new processes and materials has ensured that the field of adhesives technology is one of the more swiftly expanding manufacturing endeavors. Some excellent handbooks on adhesives already exist although there are very few indeed. However, the expansion and diversity of this field has by necessity limited the number of technologies and relevant aspects described in such volumes. This volume is no exception to such a trend.
The editors and authors do not pretend that overlaps with other similar works do not exist since basic background is often necessary to understand more advanced concepts. This volume however covers some aspects of technology that are not described in other volumes of this type. It also often looks at already reported technologies from a very different angle. It is hoped that such a volume will help to fill some of the technological gaps between the existing literature and industrial reality.
The volume is divided into four main sections, the first being an introductory overview. The remaining three sections are concerned with (1) fundamental aspects, (2) adhesive classes, and (3) some fields in which application of adhesives is very extensive. All the contributors are known specialists in their fields who practice their specialties on a daily basis. Their chapters are the results of considerable knowledge and experience in their particular niches.
It is a pleasant duty for the editors and authors, on completing a volume of this nature, to acknowledge the help willingly given by friends, colleagues, their companies, and their institutions. Without their help and encouragement most of the chapters presented would not have seen the light of day. Last, but definitely not least, our thanks go to Marcel Dekker, Inc. and its staff for originating this book, for their help and encouragement, and for prompting us to finish it.
A. PIZZI K. L. MITTAL
Page v
CONTENTS
Preface
iii
Contributors
ix
I. Review Topics
1. Historical Development of Adhesives and Adhesive Bonding
Fred A. Keimel
3
II. Fundamental Aspects
2. Theories and Mechanisms of Adhesion
J. Schultz and M. Nardin
19
3. Application of Plasma Technology for Improved Adhesion of Materials
Om S. Kolluri
35
4. Silane and Other Adhesion Promoters in Adhesive Technology
Peter Walker
47
5. Testing of Adhesives
K. L. DeVries and P. R. Borgmeier
65
6. Physical Testing of Pressure-Sensitive Adhesive Systems
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