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Greene - Sustainable plastics: environmental assessments of biobased, biodegradable, and recycled plastics

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Greene Sustainable plastics: environmental assessments of biobased, biodegradable, and recycled plastics
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Sustainable plastics: environmental assessments of biobased, biodegradable, and recycled plastics: summary, description and annotation

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A vital resource for practitioners, scientists, researchers, and students, the text includes impacts of plastics including Life Cycle Assessments (LCA) and sustainability strategies related to biobased plastics and petroleum based plastics as well as end-of-life options for petroleum and biobased plastics--;Providing guidelines for implementing sustainable practices for traditional petroleum based plastics, biobased plastics, and recycled plastics, Sustainable Plastics and the Environment explains what sustainable plastics are, why sustainable plastics are needed, which sustainable plastics to use, and how manufacturing companies can integrate them into their manufacturing operations. A vital resource for practitioners, scientists, researchers, and students, the text includes impacts of plastics including Life Cycle Assessments (LCA) and sustainability strategies related to biobased plastics and petroleum based plastics as well as end-of-life options for petroleum and biobased plastics--;1. Introduction to Sustainability -- 1.1. Sustainability Definition -- 1.2. Green Chemistry Definitions -- 1.3. Green Engineering Definitions -- 1.4. Sustainability Definitions for Manufacturing -- 1.5. Life Cycle Assessment -- 1.6. Lean and Green Manufacturing -- 1.7. Summary -- References -- Review Questions -- Review Problems -- Review Exercises -- 2. Environmental Issues -- 2.1. The Planet is Warming -- 2.2. Melting of Glaciers -- 2.3. Rising Seas -- 2.4. Causes of Global Warming -- 2.5. Ocean Pollution and Marine Debris -- 2.6. Chemical Pollution from Plastics -- 2.7. Landfill Trash -- 2.8. Summary -- References -- Review Questions -- Review Problems -- Review Exercises -- 3. Life Cycle Information -- 3.1. Life Cycle Assessment for Environmental Hazards -- 3.2. Life Cycle Assessment Definitions -- 3.3. ISO 14040/14044 Life Cycle Assessment Standards -- 3.4. Sensitivity Analysis -- 3.5. Minimal Acceptable Framework for Life Cycle Assessments.

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Sustainable plastics environmental assessments of biobased biodegradable and recycled plastics - image 1
Sustainable Plastics
Environmental Assessments of Biobased, Biodegradable, and Recycled Plastics

Joseph P. Greene

Sustainable plastics environmental assessments of biobased biodegradable and recycled plastics - image 2

Cover Design: Wiley
Cover Image: Courtesy of the author

Copyright 2014 by John Wiley & Sons, Inc. All rights reserved.

Published by John Wiley & Sons, Inc., Hoboken, New Jersey.
Published simultaneously in Canada.

No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission.

Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

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Library of Congress Cataloging-in-Publication Data:

Greene, Joseph P., 1961
Sustainable plastics : environmental assessments of biobased, biodegradable, and recycled
plastics / Joseph P. Greene.
pages cm
Includes bibliographical references and index.
ISBN 978-1-118-10481-1 (hardback)
1. Biodegradable plastics. 2. PlasticsRecycling. 3. PlasticsEnvironmental aspects.
4. Green chemistry. I. Title.
TP1180.B55G7435 2014
668.4dc23

2013051271

Preface

Plastics are one of the greatest inventions of the twentieth century. Plastics enable products to be made that meet the needs of the public for plastic applications. Plastics make life easier for all of us. We can purchase food, drink, and consumables in safe, lightweight, and clean containers and packaging made from plastic. We can drive around or be transported in a vehicle that is comfortable, pleasing to the eye, and safe thanks in part to plastics. We can communicate with small electronic devices that keep us connected with one another and also help entertain us with real and fantasy worlds.

Plastics are lightweight and easily thrown away with other heavier debris. Plastics can be recycled and reused many times. However, the lightweight benefits of plastics can cause them to be airborne and difficult for waste management companies to collect and dispose them off in landfills or other disposal environments. The lightweight plastics can occupy large volumes of landfills and can be a litter problem for land and sea. Floating plastics debris might be the final legacy of our disposal-society generation. Through education and training we can help our younger people become the sustainable generation. We can educate them in the ways of producing products and services with reduced environmental impacts. Products and services can be created with minimal waste, greenhouse gases, and pollution. This book can help provide information on creating lightweight and sustainable plastic products for our sustainable world.

Bioplastics today can be made from corn, soy, sugarcane, potato, or other renewable material source. Petroleum plastics can also be sustainable if they are made from renewable or recycled material sources. The manufacturing process also can also be sustainable. Plastics have the opportunity to define sustainable materials that are made from renewable or recycled materials sources, made with lower energy, produce less pollution, and have a low carbon footprint. Sustainable plastic materials also are recycled or composted at the end of the product service life. This book will define sustainability and sustainable materials and provide practical examples of sustainable plastics and provide examples of life cycle assessments (LCA) for these materials. This book can be used for education and training for plastics professionals and students who are interested in creating sustainable products.

Sustainable plastics can include biobased, biodegradable, and recycled plastics. LCAs will be used to provide a scientific explanation of sustainable plastics. The content of the book includes definitions of sustainability and sustainable materials, evaluations of the environmental concerns for industry, definitions of life cycle assessments, explanations of biobased and recycled plastics, and examples of sustainable plastics as defined by LCAs.

The author would like to thank Ms. Vanessa Vaquera for providing the artwork in the book.

Dedication

The author would like to dedicate this book to Dr. James O. Wilkes, Chemical Engineering Department, The University of Michigan, Ann Arbor, MI.

Glossary
ACC

American Chemistry Council

AHA

Alpha hydroxyl acid

AMS

Accelerator Mass Spectrometry (ASTM D6686)

ASTM

American Society for Testing Materials

BHET

(2-Hydroxyethyl)terephthalate

BOD

Biochemical oxygen demand (ISO 14851)

CFC

Chlorofluorocarbon

CO2eq

Carbon dioxide equivalent

DIN

German Organization for Standardization

DOE

Department of Energy

EOL

End-of-life

EPA

Environmental Protection Agency

GHG

Greenhouse gas

GPPS

General purpose polystyrene

GSI

Greene sustainability index

GWP

Global warming potential

HDPE

High density ethylene

HIPS

High impact polystyrene

LCS

Liquid Scintillation Counting (ASTM D6686)

IRMS

Isotope Ratio Mass Spectrometry (ASTM D6686)

ISBM

Integrated stretch blow molding

LCA

Life cycle assessment

LCI

Life cycle inventory

LDPE

Low density polyethylene

MEG

Mono-ethylene glycol

MRF

Materials recovery facility

MSW

Municipal solid waste

OPS

Oriented polystyrene sheet

PET

Polyethylene terephthalate

PGA

Poly glycolic acid

PHA

Poly-hydroxy-alkanoate

PHB

Poly-hydroxy-butyrate

PHBV

Poly-hydroxy-valerate

PLA

Poly lactic acid

POCP

Photochemical Ozone Creation Potential

PP

Polypropylene

PS

Polystyrene

PVC

Poly vinyl chloride

RDF

Refused derived fuel

USDA

United States Department of Agriculture

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