Anne Myers Kelley - Condensed-Phase Molecular Spectroscopy and Photophysics

1. Chapter 4
2. Chapter 8
3. Appendix 1

1. Chapter 1
2. Chapter 2
3. Chapter 4
4. Chapter 5
5. Chapter 6
6. Chapter 7
7. Chapter 8
8. Chapter 9
9. Chapter 10
10. Chapter 11
11. Chapter 12
12. Chapter 13
13. Chapter 14
14. Chapter 15
15. Chapter 16
16. Chapter 17
17. Chapter 18
18. Chapter 19
19. Chapter 20
20. Chapter 21
21. Chapter 22

Second Edition

Anne Myers Kelley

University of California, Merced, USA

This edition first published 2023
2023 John Wiley & Sons, Inc.

Edition History
John Wiley & Sons (1e, 2012)

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Library of Congress CataloginginPublication Data:

Names: Kelley, Anne Myers, 1958- author.
Title: Condensed-phase molecular spectroscopy and photophysics / Anne Myers
Kelley, University of California, Merced, USA.
Description: Second edition. | Hoboken, NJ : John Wiley & Sons, Inc., 2023. | Includes bibliographical references and index.
Identifiers: LCCN 2022017132 (print) | LCCN 2022017133 (ebook) | ISBN 9781119829263 (cloth) | ISBN 9781119829270 (adobe pdf) | ISBN 9781119829287 (epub)
Subjects: LCSH: Condensed matter--Spectra. | Molecular spectroscopy. | Quantum theory. | Semiconductors--Spectra.
Classification: LCC QC173.458.S64 K47 2022 (print) | LCC QC173.458.S64 (ebook) | DDC 543/.54--dc23 /eng20220822

LC record available at https://lccn.loc.gov/2022017132
LC ebook record available at https://lccn.loc.gov/2022017133

Cover Image: Courtesy of Anne Myers Kelley
Cover Design: Wiley

Ten years ago I set out to convert 25years' worth of lecture notes into a textbook suitable for use in a graduatelevel course on molecular spectroscopy with an emphasis on condensedphase topics. That became the first edition of this book, published in 2013. In the following years, I have taught graduate spectroscopy from this book several more times and have given it to a number of students as a general spectroscopy reference, and I have become painfully aware of a number of changes and additions that would improve the book. I finally decided to jump in and write a second edition.

The most significant changes between the first and second editions are several new chapters and sections introducing new material. There are now short chapters on atomic spectroscopy and rotational spectroscopy, two topics that were left out entirely from the first edition. While usually not relevant in condensedphase spectroscopy, I felt that these two topics should be included for completeness. Sections on stimulated Raman scattering and hyperRaman spectroscopy have been added, as well as new chapters on twodimensional spectroscopy, singlemolecule spectroscopy, and timedependent formulations of steadystate spectroscopy. Much of my research career has involved developing and using the timedependent picture of steadystate resonance Raman spectroscopy. I deliberately left that topic out of the first edition feeling that it was too specialized for a general spectroscopy text, but have decided to add it here for those who would like an introduction to the topic.

I have made a number of other changes to the text that include fixing a few errors, rewording and reorganizing explanations, and adding color to figures where it helps with clarity. I have also changed from denoting operators with outline font which is very difficult to reproduce when writing on a chalkboard or whiteboard to the more standard notation of hats for operators.

Finally, I have reorganized the entire book by dividing it into three sections. on crystals.

Like the first edition, this remains primarily a theoretical spectroscopy book. Experimental techniques are discussed only to the extent necessary to understand the resulting data. This is partly a practical choice, as the topic of experimental techniques in spectroscopy would be a fulllength book in its own right. In addition, I wanted to produce a book that would not go out of date too quickly. Experimental techniques evolve as new technologies are developed, and while many of the elements of experimental spectroscopy are essentially the same as when I entered the field over 40years ago, others have changed drastically. While new technologies enable new experiments that may require additional theoretical developments, the underlying spectroscopic theory seems unlikely to become obsolete anytime soon.