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David A. Young - Phase Diagrams of the Elements

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    Phase Diagrams of the Elements
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The behavior of solid and liquid matter at high pressures and temperatures is best described in a phase diagram, which shows the regions of stability of different phases of the material. Thanks to the diamond-anvil cell, which has made possible much higher pressures, and to new and very accurate theoretical models and methods, Phase Diagrams of the Elements presents the most up-to-date information on the phase behavior of all the chemical elements from hydrogen to fermium.The book summarizes, with the aid of tables and illustrations, the experimental data and the theoretical calculations. Each element is discussed in a separate section. Other chapters deal with methods, the liquid-vapor transition, and an overview of the elements. While comprehensively reviewing all that has been done in this important area, the author also points to questions that need much more experimental and theoretical work.

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David A. Young
Phase Diagrams of the Elements

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title Phase Diagrams of the Elements author Young D A - photo 1
title:Phase Diagrams of the Elements
author:Young, D. A.
publisher:University of California Press
isbn10 | asin:0520074831
print isbn13:9780520074835
ebook isbn13:9780585305011
language:English
subjectPhase diagrams, High pressure (Science)
publication date:1991
lcc:QD503.Y68 1991eb
ddc:541.3/63
subject:Phase diagrams, High pressure (Science)
Page iii
Phase Diagrams of the Elements
David A. Young
Page iv Permission has been granted by the publisher for the reprinting of - photo 2
Page iv
Permission has been granted by the publisher for the reprinting of Figure 15.17 from Solid State Physics by Neil W. Ashcroft and N. David Mermin, copyright 1976 by Saunders College Publishing, a division of Holt, Rinehart and Winston, Inc.
University of California Press
Berkeley and Los Angeles, California
University of California Press
Oxford, England
Copyright 1991 by The Regents of the University of California
Library of Congress Cataloging-in-Publication Data
Young, D. A. (David A.), 1942
Phase diagrams of the elements/David A. Young
p. cm.
Includes bibliographical references and index.
ISBN 0-520-07483-1
1. Phase diagrams. 2. High pressure (Science) I. Title.
QD503.Y68 1991 90-25978
541.3'63dc20 CIP
Printed in the United States of America
1 2 3 4 5 6 7 8 9
The paper used in this publication meets the minimum requirements of American National Standard for Information SciencesPermanence of Paper for Printed Library Materials, ANSI Z39.48-1987 Picture 3
Page v
Contents
Preface
xi
Chapter 1
Introduction
1
Chapter 2
Experimental Methods
8
Picture 4
2.1 Introduction
8
Picture 5
2.2 Static High Pressure
9
Picture 6
2.3 Dynamic High Pressure
14
Picture 7
2.4 Isobaric Heating
18
Picture 8
2.5 Discussion
19
Chapter 3
Theoretical Methods
23
Picture 9
3.1 Introduction
23
Picture 10
3.2 Electron-Band-Structure Calculations
23
Picture 11
3.3 Interaction Potentials
27
Picture 12
3.4 Statistical Models
29
Picture 13
3.5 Thermodynamics of Phase Transitions
33
Picture 14
3.6 Melting
35
Picture 15
3.7 Solid-Solid Transitions
41
Picture 16
3.8 Liquid-Liquid Transitions
43
Picture 17
3.9 Generalized Phase Diagrams
44
Picture 18
3.10 Extreme Conditions
44
Picture 19
3.11 Discussion
45
Chapter 4
Hydrogen
48
Picture 20
4.1 Introduction
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