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Ferdinand Rodriguez - Principles of polymer systems, Volume 1

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Principles of polymer systems, Volume 1: summary, description and annotation

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The Fifth Edition of Principles of Polymer Systems has been completely revised and updated. The chemical engineering perspective has been retained and strengthened, and the broad applications of polymers in chemistry and materials science have been addressed. The theoretical basis for various topics has been deepened and strengthened and several new topics are addressed. These changes reflect the rapidly growing recognition by all scientists and engineers of the role polymers play in industry. Electronics and medicine are representative areas that require more than a passing knowledge of macromolecular principles. Both areas receive attention in this edition. The end-of-chapter problems in the book have been completely replaced with the new problems. A solutions manual will be available to qualified instructors.

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Cover

title Principles of Polymer Systems 5Th Ed author Rodriguez - photo 1
title:Principles of Polymer Systems 5Th Ed.
author:Rodriguez, Ferdinand
publisher:Taylor & Francis Routledge
isbn10 | asin:1560329394
print isbn13:9781560329398
ebook isbn13:9780203428504
language:English
subjectPolymers.
publication date:2003
lcc:TP156.P6R62 2003eb
ddc:668.9
subject:Polymers.

Page i

Principles of Polymer Systems

Fifth Edition

Page ii

This page intentionally left blank.

Page iii

Principles of Polymer Systems

Fifth Edition

Ferdinand Rodriguez
Claude Cohen
Christopher Ober
Lynden A.Archer

Cornell University
Ithaca, NY 148535201

New York London Page iv Denise TSchanck Vice President Robert LRogers - photo 2

New York London

Page iv

Denise T.Schanck, Vice President
Robert L.Rogers Senior Editor
Liliana Segura, Editorial Assistant
Savita Poornam, Marketing Manager
Maria Corpuz, Marketing Assistant

Dennis P.Teston, Production Director
Anthony Mancini Jr., Production Manager
Brandy Mui, STM Production Editor
Mark Lerner, Art Manager
Daniel Sierra, Cover Designer

Published in 2003 by
Taylor & Francis
29 West 35th Street
New York, NY 10001

This edition published in the Taylor & Francis e-Library, 2005.


To purchase your own copy of this or any of Taylor & Francis or Routledges collection of thousands of eBooks please go to www.eBookstore.tandf.co.uk.

Published in Great Britain by
Taylor & Francis
11 New Fetter Lane
London EC4P 4EE
www.taylorandfrancis.co.uk

Cover Image: Polarized light micrograph of a thin-film preparation of recrystallized polyethylene glycol captured with a first-order retardation plate to indicate the sign of birefringence.
Courtesy of Michael W.Davidson, Florida State University.

Copyright 2003 by Taylor & Francis Books, Inc.

All rights reserved. No part of this book may be reprinted or reproduced or utilized in any
form or by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying and recording, or in any information storage or retrieval system, without permission in writing from the publisher.

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data
Principles of polymer systems.5th ed./Ferdinand Rodriguez[et al.].
p. cm.
Rev. ed. of: Principles of polymer systems/Ferdinand Rodriguez. 4th ed. c1996.
Includes bibliographical references and index.
ISBN 1-56032-939-4
1. Polymers. I. Rodriguez, Ferdinand, 1928 II. Rodriguez, Ferdinand, 1928 Principles
of polymer systems.
TP156.P6R62 2003
668.9dc21

2002043026

ISBN 0-203-42850-1 Master e-book ISBN

ISBN 0-203-44639-9 (OEB Format)

ISBN 1-56032-939-4 (Print Edition)

Page v

CONTENTS

Preface

xi

Preface to the First Edition

xiii

Introduction

1.1 Polymers

1.2 Applications of Polymers

1.3 Polymer-Based Industries

1.4 Feedstocks for Polymers

1.5 Polymer Science and Technology

1.6 Trends

Keywords

Problems

References

Basic Structures of Polymers

2.1 Classification Schemes

2.2 Bonding

2.3 Single Molecules

2.4 Network Molecules

2.5 Thermodynamics of Binary Systems

2.6 Cohesive Energy Density and Solubility Parameter

Appendix

Keywords

Problems

References

Page vi

Physical States and Transitions

3.1 Physical States

3.2 Conformation of Single Chains in Solution

3.3 Phase Separation in Polymer Mixtures

3.4 Transitions in Pure Polymers

3.5 Amorphous Polymers

3.6 Plasticization

3.7 Crystallinity

3.8 Conformation of Single Chains in Crystals

3.9 Spherulites and Drawing

3.10 Crystallization

3.11 Transition Temperatures

3.12 Block Copolymers

3.13 Liquid Crystal Polymers

3.14 Gels

Keywords

Problems

References

Polymer Formation

4.1 Polymerization Reactions

4.2 Functionality

4.3 Step and Chain Growth Polymerizations

4.4 Chain Polymerization

4.5 Ionic Polymerization

4.6 Controlled Radical Polymerization

4.7 Insertion Polymerization

4.8 Step Growth Polymerization

4.9 Ring-Opening Polymerization

4.10 Copolymerization

4.11 Biosynthesis of Polymers

4.12 Polymer Modification

Keywords

Problems

References

Polymerization Processes

5.1 Design Criteria

5.2 Bulk Polymerization

5.3 Solution Polymerization

5.4 Suspension Polymerization

5.5 Emulsion Polymerization

5.6 Comparison of Polymerization Methods

Page vii

Keywords

Problems

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