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Joel R. Fried - Polymer Science and Technology

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The Definitive Guide to Polymer Principles, Properties, Synthesis, Applications, and Simulations

Now fully revised, Polymer Science and Technology, Third Edition, systematically reviews the fields current state and emerging advances. Leading polymer specialist Joel R. Fried offers modern coverage of both processing principles and applications in multiple industries, including medicine, biotechnology, chemicals, and electronics.

This editions new and expanded coverage ranges from advanced synthesis to the latest drug delivery applications. New topics include controlled radical polymerization, click chemistry, green chemistry, block copolymers, nanofillers, electrospinning, and more.

A brand-new chapter offers extensive guidance for predicting polymer properties, including additional coverage of group correlations, and new discussions of the use of topological indices and neural networks. This is also the first introductory polymer text to fully explain computational polymer science, including molecular dynamics and Monte Carlo methods. Simulation concepts are supported with many application examples, ranging from prediction of PVT values to permeability and free volume.

Fried thoroughly covers synthetic polymer chemistry; polymer properties in solution and in melt, rubber, and solid states; and all important categories of plastics. This revised edition also adds many new calculations, end-of-chapter problems, and references.

In-depth coverage includes

  • Polymer synthesis: step- and chain-growth; bulk, solution, suspension, emulsion, solid-state, and plasma; ionic liquids, and macromers; and genetic engineering
  • Amorphous and crystalline states, transitions, mechanical properties, and solid-state characterization
  • Polymers and the environment: degradation, stability, and more
  • Additives, blends, block copolymers, and compositesincluding interpenetrating networks, nanocomposites, buckyballs, carbon nanotubes, graphene, and POSS
  • Biopolymers, natural polymers, fibers, thermoplastics, elastomers, and thermosets
  • Engineering and specialty polymers, from polycarbonates to ionic polymers and high-performance fibers
  • Polymer rheology, processing, and modeling
  • Correlations and simulations: group contribution, topological indices, artificial neural networks, molecular dynamics, and Monte Carlo simulations

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Polymer Science and Technology

Third Edition

Joel R. Fried

Polymer Science and Technology - image 1

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Library of Congress Cataloging-in-Publication Data
Fried, Joel R.
Polymer science and technology / Joel R. Fried.Third edition.
pages cm
Includes bibliographical references and index.
ISBN 978-0-13-703955-5 (hardcover : alk. paper)
1. Polymers. 2. Polymerization. I. Title.
QD381.F73 2014
668.9dc23 2014000967

Copyright 2014 Pearson Education, Inc.

All rights reserved. Printed in the United States of America. This publication is protected by copyright, and permission must be obtained from the publisher prior to any prohibited reproduction, storage in a retrieval system, or transmission in any form or by any means, electronic, mechanical, photocopying, recording, or likewise. To obtain permission to use material from this work, please submit a written request to Pearson Education, Inc., Permissions Department, One Lake Street, Upper Saddle River, New Jersey 07458, or you may fax your request to (201) 236-3290.

ISBN-13: 978-0-13-703955-5
ISBN-10: 0-13-703955-7

Text printed in the United States on recycled paper at Courier Corporation in Westford, Massachusetts.
First printing, May 2014

To my parents, who provided the opportunities,
support, and guidance, and to my wife, Ava, and sons,
Marc and Aaron, for their love, patience, and
understanding
.

Preface

Polymer Science and Technology, Third Edition, provides new and expanded coverage in a number of areas of contemporary interest in polymer science and technology. In particular, , on polymers for advanced technologies. In addition, an entirely new chapter on correlations and simulation methods in polymer science has been added. This new chapter includes expanded treatment of group-correlation methods to predict polymer properties that has previously appeared in a number of earlier chapters in the second edition. Totally new is the inclusion of topological indices and artificial neural networks to predict properties. For the first time in an introductory polymer textbook, the fundamentals and applications of computational polymer science including the use of molecular dynamics and Monte Carlo methods are presented with a number of examples and exercise problems.

Joel R. Fried
Tallahassee, Florida

About the Cover Illustration

The cover illustration shows a molecular simulation of a blend of 37 wt% of functionalized C60 fullerene, PCBM, (space-filling representation) in an amorphous cell containing a thiophene copolymer. This system has been reported to provide attractive photovoltaic properties for polymeric photovoltaic cells. Simulations of polymeric systems are described in of this third edition.

Preface to the Second Edition

The second edition provides new and expanded coverage of important topics in polymer science and engineering and includes additional example calculations, homework problems, and bibliographic references. Additional topics in the treatment of polymer synthesis (.

Although the intended audience for this text is advanced undergraduates and graduate students in chemical engineering, the coverage of polymer science fundamentals describes polymers used in areas of advanced technology including membrane separations, electrolytes for batteries and fuel cells, controlled drug release, nonlinear optical applications, and light-emitting diodes and displays. This coverage may be used as reference material for scientists and engineers and provides a basis for short courses in such areas as membrane science and technology and polymer physics.

Joel R. Fried
Cincinnati, Ohio

Preface to the First Edition

At least dozens of good introductory textbooks on polymer science and engineering are now available. Why then has yet another book been written? The decision was based on my belief that none of the available texts fully address the needs of students in chemical engineering. It is not that chemical engineers are a rare breed, but rather that they have special training in areas of thermodynamics and transport phenomena that is seldom challenged by texts designed primarily for students of chemistry or materials science. This has been a frustration of mine and of many of my students for the past 15 years during which I have taught an introductory course, Polymer Technology, to some 350 chemical engineering seniors. In response to this perceived need, I had written nine review articles that appeared in the SPE publication Plastics Engineering from 1982 to 1984. These served as a hard copy for my students to supplement their classroom notes but fell short of a complete solution.

In writing this text, it was my objective to first provide the basic building blocks of polymer science and engineering by coverage of fundamental polymer chemistry and materials topics given in . In all, this has been an ambitious undertaking and I hope that I have succeeded in at least some of these goals.

Although the intended audience for this text is advanced undergraduates and graduate students in chemical engineering, the coverage of polymer science fundamentals (, intended as survey chapters of the principal categories of polymerscommodity thermoplastics and fibers, network polymers (elastomers and thermoplastics), and engineering and specialty polymersmay be included to supplement and reinforce the material presented in the chapters on fundamentals and should serve as a useful reference source for the practicing scientist or engineer in the plastics industry.

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