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Louis D. Quin - A Guide to Organophosphorus Chemistry

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An authoritative and comprehensive introduction to organophosphorus chemistry The broad, exciting field of organophosphorus chemistry has grown tremendously over the last few decades, with a wealth of opportunities for research and applications development. A Guide to Organophosphorus Chemistry offers chemists in academia and industry complete, up-to-date coverage of the fundamentals with an eye on future developments in this area. Internationally recognized authority Louis D. Quin extends his experienced perspective and insight on the topic by:* Surveying the most important phosphorus-containing functional groups* Including representative methods of synthesis, plus references to detailed synthetic procedures* Outlining advances in stereochemical aspects of phosphorus chemistry* Covering areas of current research, such as unusual coordination states, heterocycles, applications of 31P-NMR, and other spectroscopic methods* Providing numerous references to important review articles and recent literature* Presenting electronic mechanisms and reactive intermediates where established* Discussing the importance of phosphorus compounds in living systems and in agricultural applicationsLiberally illustrated with equations and structural formulas, A Guide to Organophosphorus Chemistry presents a virtually unparalleled introduction to the subject matter, making it an indispensable instructional tool for aspiring chemists and practicing chemists alike.

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title A Guide to Organophosphorus Chemistry author Quin Louis D - photo 1

title:A Guide to Organophosphorus Chemistry
author:Quin, Louis D.
publisher:John Wiley & Sons, Inc. (US)
isbn10 | asin:0471318248
print isbn13:9780471318248
ebook isbn13:9780585276175
language:English
subjectOrganophosphorus compounds.
publication date:2000
lcc:QD305.P46Q56 2000eb
ddc:547/.07
subject:Organophosphorus compounds.
Page iii
A Guide to Organophosphorus Chemistry
Louis D. Quin
Distinguished Visiting Professor
Department of Chemistry
University of North Carolina At Wilmington
and
Professor Emeritus, Duke University and University of Massachusetts
Structural Illustrations by
Gyngyi Szakl Quin
Research Scientist
University of North Carolina at Wilmington
Page iv This book is printed on acid-free paper Copyright 2000 by - photo 2
Page iv
This book is printed on acid-free paper. Picture 3
Copyright 2000 by John Wiley & Sons. All rights reserved.
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4744. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley Sons, Inc., 605 Third Avenue, New York, NY 10158-0012, (212) 850-6011, fax (212) 850-6008, E-Mail: PERMREQ@WILEY.COM.
For ordering and customer service, call 1-800-CALL-WILEY
Library of Congress Cataloging-in-Publication Data:
Quin, Louis D., 1928
A guide to organophosphorus chemistry / by Louis D. Quin.
p. cm.
Includes index.
ISBN 0-471-31824-8 (alk. Paper)
1. Organophosphorous compounds.
I. Title.
QD305.P46Q56 2000
547'.07-dc21 99-43429
Printed in the United States of America.
10 9 8 7 6 5 4 3 2 1
Page v
Contents
Preface
ix
1
The Nature of Organophosphorus Chemistry
1
2
Some General Considerations of Organophosphorus Compounds
8
Picture 4
2.A. Organization of Compounds by the Bonding to Phosphorus
8
Picture 5
2 B. Oxidation State Relationships
10
Picture 6
2.C. Stability of the CarbonPhosphorus Bond
11
Picture 7
2.D. Importance and Characteristics of the Phosphory1 (P=O) Group
12
Picture 8
2.E. 1,2-Dipoles (Ylides) Containing Phosphorus
15
Picture 9
2.F. The 5-Coordinate State of Phosphorus
17
Picture 10
2.G. The POH to P(O)H Rearrangement with 3-Coordinate Phosphorus
20
Picture 11
2.H. Phosphorus Bonds to Heteroatoms (X, S, OR, NR2)
21
Picture 12
2.I. Analogies between the Chemistry of Phosphorus Compounds and That of Related Elements (N, S, C)
23
Picture 13
2.J. Incorporation of Phosphorus in Rings
25
Picture 14
2.K. Reactive Intermediates and Reaction Mechanisms
27
Picture 15
2.L. Safety in the Handling of Organophosphorus Compounds
34

Page vi
Picture 16
2.M. Important Literature Resources in Phosphorus Chemistry
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