Alexandre Alexakis - Copper-Catalyzed Asymmetric Synthesis
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The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications.
This is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies.
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The Editors
Prof. Dr. Alexandre Alexakis
University of Geneva
Dept. of Organic Chemistry
Postfach 30
1211 Genve 4
Switzerland
Prof. Dr. Norbert Krause
University Dortmund
Organic Chemistry II
Otto-Hahn-Str. 6
44227 Dortmund
Germany
Prof. Dr. Simon Woodward
University Of Nottingham
School of Chemistry
University Park
Nottingham NG7 2RD
United Kingdom
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The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at .
2014 Wiley-VCH Verlag GmbH & Co. KGaA, Boschstr. 12, 69469 Weinheim, Germany
All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form by photoprinting, microfilm, or any other means nor transmitted or translated into a machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law.
Print ISBN: 978-3-527-33204-5
ePDF ISBN: 978-3-527-66460-3
ePub ISBN: 978-3-527-66459-7
mobi ISBN: 978-3-527-66458-0
oBook ISBN: 978-3-527-66457-3
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