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Sebastian Koltzenburg Michael Maskos - Polymer Chemistry

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Sebastian Koltzenburg Michael Maskos Polymer Chemistry

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Springer-Verlag Berlin Heidelberg 2017
Sebastian Koltzenburg , Michael Maskos and Oskar Nuyken Polymer Chemistry
1. Introduction and Basic Concepts
Sebastian Koltzenburg 1, Michael Maskos 2 and Oskar Nuyken 3
(1)
Functional Biopolymers, BASF SE, GMM/B - B001, Ludwigshafen, Germany
(2)
Fraunhofer ICT-IMM, Mainz, Germany
(3)
Garching, Germany
Among the many areas of chemistry, polymer science is a comparatively new field. The empirical use of polymeric materials made from natural substances has been documented for centuries; however, only the pioneering work of the late Hermann Staudinger (), a Nobel laureate, in the 1920s provided the basis for a systematic understanding of this class of materials. In the decades since then, polymer science has developed to become both technically demanding and industrially extremely important. In particular, polymer science is characterized by its interdisciplinary nature:
  • Most technologically relevant macromolecules are based on a carbon backbone and thus belong in the realm of organic chemistry .
  • Approximately half of all polymers produced today are synthesized using organo-metallic catalysts.
  • A description of the behavior of both solid polymers and their solutions is now based on well-established physical and physicochemical theories .
  • Because macromolecules are often used in the area of classical materials, processing and molding of polymers is an essential step in the production of finished products. Thus, engineering science is also important. In medical technologies, polymers are used in highly specialized applications, such as artificial heart valves, eye lenses, or as materials for medical devices.
Last but not least, as well as the vast and significant use of synthetic polymers, macromolecules are of crucial biological importance. Undoubtedly the most important polymer in the worldwithout which human existence would not be possibleis DNA. Without its polymeric nature, DNA could not fulfill its essential role as the memory molecule of living systems. If the molecules were not linked to a polymeric strand, DNA would be nothing more than a mixture of four different bases with no defined structure and therefore without biological function. In addition to the millions of tons of natural rubber processed annually, further examples of biopolymers essential to life include proteins that catalyze chemical reactions as enzymes, form membranes, or act as antibodies differentiating between friend and foe.
This chapter deals with the basic concepts and definitions of polymer science and especially the most important question that a natural scientist can ask: Why? In particular, why should one take an interest in this field? It is shown that polymers constitute a class of materials that not only make an essential contribution to the existence of life in the form of biological macromolecules, but without which, thanks to their myriad technical applications, our modern daily life would be no longer conceivable.
1.1 Polymers: Unique Materials
Even if we restrict ourselves to the field of non-biogenic, traditional materials, macromolecules are a material class of unparalleled versatility. However, the range of properties covered by polymeric materials is much broader than that of traditional materials. Thus, for example:
  • Glass fiber reinforced plastics can have tensile strengths that rival, e.g., steel, whereas other polymers such as polyurethane foams can be used as soft cushions or mattresses.
  • Most plastics are electrical insulators, but highly conjugated polymers have also been synthesized with specific conductivities of the same order of magnitude of those of highly conductive metals (Naarmann and Theophilou ).
  • The density of porous polymeric materials can be varied across a very wide range. In particular, from polymer foams such as Styrofoam, extremely lightweight articles can be produced.
  • The melting point of polymers can also be greatly modified by varying the macromolecular architecture. Some polymers can be physically described as highly viscous melts even at room temperature, whereas other polymers have melting points of several hundred degrees Celsius, and can be heated to red heat or sintered. Of course, the temperature range of the melting or softening point is critical for the temperature at which a material can be used or processed. On the one hand, a high melting point allows a high service temperature but requires a lot of energy to process the molten material into the final shape. For many materials in everyday life, which are only used at room temperature, a low melting point is an advantage because they can be processed much more resource-efficiently than materials with a high melting point. Here, too, the unrivaled variability that polymers offer is often a decisive and advantageous factor.
Because of their great versatility and their resulting unique material properties, synthetic polymeric materials have become indispensable in our daily lives. Many familiar applications can only be realized using macromolecular materials:
  • The electrical and electronics industries in their current form are difficult to envisage without polymers. This statement includes seemingly trivial applications such as the sheathing for electric cablesno other non-polymeric substance class provides materials that are both flexible and at the same time act as electrical insulators. Even in technically much more demanding applications, such as the manufacture of solar cells, LEDs, or integrated microchips, polymers play a crucial role, e.g., as etching masks, protective coatings, dielectrics, or fiber optics.
  • The modern automobile would also be unthinkable without polymers. All motor vehicles manufactured today are covered with a polymer layerthe so-called clearcoat . In addition, polymers, from which, for example, the tires, dashboard, seat cushions, and bumpers are constructed, make a major contribution to reducing the weight of the vehicle, thus limiting the fuel consumption.
  • The construction industry has also benefited enormously from this relatively young class of materials. Polymers in the form of insulating foams reduce the energy consumption of buildings, serve as conduits for water supply and sanitation, and provide a weather-resistant alternative to the use of exterior wood.
  • As packaging, polymers are now irreplaceable, especially for food packaging or as shock absorbing material for goods in transit.
Polymers find applications not just as classical materials but also as, mostly soluble, active ingredients and functional additives. As such, they often go unnoticed because they are not the actual material but rather, often in relatively small amounts, responsible for the appearance of something. Thus, polymers can be found in modern detergents, cosmetics, or pharmaceutical products. They are also used in water treatment and paper production. In the latter capacity, macromolecules as functional polymers are discussed in detail in Chap..
1.2 Definition of Terminology and Basic Concepts
In the following section a brief introduction to the basic concepts of polymer science is given.
1.2.1 Fundamentals
The term polymer refers by definition to molecules formed from a number of building blocks, called monomers , usually connected by covalent bonds. The prefix poly comes from the Greek word for many whereas the Greek prefix mono means single and refers here to a single block. In the synthesis of many polymers, monomers are linked together in the same manner to form a single chain consisting of covalently connected repeating units (see Fig. ).
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