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Yuri E. Kirsh - Water Soluble Poly-N-Vinylamides: Synthesis and Physicochemical Properties

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Water Soluble Poly-N-Vinylamides: Synthesis and Physicochemical Properties: summary, description and annotation

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Despite the growing interest in this new generation of water soluble carbon-chain polymers, there are few books available covering their physicochemical properties. Professor Kirsh has addressed this by writing a book which brings together data on their synthesis, properties and applications. The best known of the group is poly-N-vinylpyrrolidone (PVP), discovered in Germany in 1939, hence this book concentrates on PVP and the correlation of its properties with other poly-N-vinylamides. Poly-N-vinylamides are widely used in the creation of many synthetic polymeric materials and recent discoveries have increased their use in medicine and biotechnology. This book will therefore appeal to a wide readership from polymer and materials scientists, through to biotechnologists and those working in the pharmaceutical and cosmetics industries.

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title Water-soluble Poly-N-vinylamides Synthesis and Physicochemical - photo 1

title:Water-soluble Poly-N-vinylamides : Synthesis and Physicochemical Properties
author:Kirsh, IU. E.
publisher:John Wiley & Sons, Inc. (US)
isbn10 | asin:047197630X
print isbn13:9780471976301
ebook isbn13:9780585362267
language:English
subjectPolyvinylamides.
publication date:1998
lcc:QD383.V56K57 1998eb
ddc:547/.042
subject:Polyvinylamides.
Page iii
Water Soluble Poly-N-Vinylamides
Synthesis and Physicochemical Properties
Yury E. Kirsh
Karpov Institute of Physical Chemistry, Moscow, Russia
Page iv Copyright 1998 John Wiley Sons Ltd Baffins Lane - photo 2
Page iv
Copyright 1998
John Wiley & Sons Ltd,
Baffins Lane, Chichester,
West Sussex PO19 1UD, England
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International (+44) 1243 779777
e-mail (for orders and customer service enquiries): cs-books@wiley.co.uk
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or http://www.wiley.com

All rights Reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except under the terms of the Copyright Designs and Patents Act 1988 or under the terms of a licence issued by the Copyright Licensing Agency, 90 Tottenham Court Road, London W1P 9HE, UK, without the permission in writing of the Publisher.
Other Wiley Editorial Offices
John Wiley & Sons, Inc., 605 Third Avenue,
New York, NY 10158-0012, USA
WILEY-VCH VerlagGmbH, Pappelallee 3,
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John Wiley & Sons (Canada) Ltd, 22 Worcester Road,
Rexdale, Ontario M9W 1L1, Canada
Library of Congress Cataloging-in-Publication Data
Kirsh, Yury E.
Water soluble poly-N-vinylamides : synthesis and physicochemical
properties / Yury E. Kirsh.
p. cm.
Includes bibliographical references (p. ) and index.
ISBN 0-471-97630-X (alk. paper)
1. Polyvinylamides. I. Title.
QD383.V56K57 1998
547' .042dc21 97-17696
CIP
British Library Cataloguing in Publication Data
A catalogue record for this book is available from the British Library
ISBN 0 471 97630 X
Typeset in 10/12pt Times by Thomson Press (India) Ltd, New Delhi
Printed and bound in Great Britain by Antony Rowe Ltd., Chippenham, Wilts.
This book is printed on acid-free paper responsibly manufactured from sustainable forestry, in which at least two trees are planted for each one used for paper production
Page v
Contents
Preface
vii
Introduction
1
1
N-Vinylamides: Synthesis, Conformation, and Electronic State
3
Picture 3
1.1 Synthesis of N-Vinyllactams and N-Vinylamides of Aliphatic Carboxylic Acids
3
Picture 4
1.2 Conformations of Side Substituents
16
Picture 5
1.3 Theoretical Conformational Analysis and Monomer Association of N-Vinylamides of Aliphatic Carboxylic Acids
21
Picture 6
1.4 Conformation of Rings in N-Vinyllactams
24
Picture 7
1.5 Electronic State of Monomers
30
2
Radical Polymerization
36
Picture 8
2.1 Previous Study of N-Vinylpyrrolidone Polymerization
36
Picture 9
2.2 Initiators and Reactions with Its Participation
37
Picture 10
2.3 Solvent Effects
41
Picture 11
2.4 Microstructure of the Polymer Chain and Conformations of Side Residues
48
Picture 12
2.5 Polymerization in the Presence of Hydrogen Peroxide
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