John Newman - Electrochemical Systems

1. Chapter 2
2. Chapter 4
3. Chapter 6
4. Chapter 7
5. Chapter 8
6. Chapter 9
7. Chapter 11
8. Chapter 12
9. Chapter 14
10. Chapter 17
11. Chapter 18
12. Chapter 20
13. Chapter 22
14. Appendix B

1. Chapter 1
2. Chapter 2
3. Chapter 3
4. Chapter 4
5. Chapter 6
6. Chapter 7
7. Chapter 8
8. Chapter 9
9. Chapter 11
10. Chapter 12
11. Chapter 13
12. Chapter 14
13. Chapter 15
14. Chapter 17
15. Chapter 18
16. Chapter 19
17. Chapter 21
18. Chapter 22
19. Chapter 23
20. Chapter 24
21. Appendix C

THE ELECTROCHEMICAL SOCIETY SERIES

The Electron Microprobe

Edited by T. D. McKinley, K. F. J. Heinrich, and D. B. Wittry

Chemical Physics of Ionic Solutions

Edited by B. E. Conway and R. G. Barradas

HighTemperature Materials and Technology

Edited by Ivor E. Campbell and Edwin M. Sherwood

Alkaline Storage Batteries

S. Uno Falk and Alvin J. Salkind

The Primary Battery (in Two Volumes)

Volume I

Edited by George W. Heise and N. Corey Cahoon

Volume II

Edited by N. Corey Cahoon and George W. Heise

ZincSilver Oxide Batteries

Edited by Arthur Fleischer and J. J. Lander

LeadAcid Batteries

Hans Bode

Translated by R. J. Brodd and Karl V. Kordesch

Thin FilmsInterdiffusion and Reactions

Edited by J. M. Poate, M. N. Tu, and J. W. Mayer

Lithium Battery Technology

Edited by H. V. Venkatasetty

Quality and Reliability Methods for Primary Batteries

P. Bro and S. C. Levy

Techniques for Characterization of Electrodes and Electrochemical Processes

Edited by Ravi Varma and J. R. Selman

Electrochemical Oxygen Technology

Kim Kinoshita

Synthetic Diamond: Emerging CVD Science and Technology

Edited by Karl E. Spear and John P. Dismukes

Corrosion of Stainless Steels, Second Edition

A. John Sedriks

Semiconductor Wafer Bonding: Science and Technology

Q.Y. Tong and U. Gscle

Fundamentals of Electrochemistry, Second Edition

V. S. Bagotsky

Fundamentals of Electrochemical Deposition, Second Edition

Milan Paunovic and Mordechay Schlesinger

Uhlig's Corrosion Handbook, Third Edition

Edited by R. Winston Revie

Fuel Cells: Problems and Solutions

Vladimir S. Bagotsky

Lithium Batteries: Advanced Technologies and Applications

Edited by B. Scrosati, K. M. Abraham, W. A. van Schalkwijk, and J. Hassoun

Modern Electroplating, Fifth Edition

Edited by Mordechay Schlesinger and Milan Paunovic

Electrochemical Power Sources: Batteries, Fuel Cells, and Supercapacitors

By V. S. Bagotsky, A. M. Skundin, and Y. M. Volfkovic

Molecular Modeling of Corrosion Processes: Scientific Development and Engineering Applications

Edited by C. D. Taylor and P. Marcus

Atmospheric Corrosion, Second Edition

Christofer Leygraf, Inger Odnevall Wallinder, Johan Tidblad, and Thomas Graedel

Electrochemical Impedance Spectroscopy, Second Edition

Mark E. Orazem and Bernard Tribollet

Electrochemical Systems, Fourth Edition

John Newman and Nitash P. Balsara

Fourth Edition

JOHN S. NEWMAN and NITASH P. BALSARA

University of California, Berkeley

This edition first published 2021

2021 John Wiley & Sons Inc.

Edition History

John Wiley & Sons Inc. (3e, 2004).

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In view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. While the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials, or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

Library of Congress CataloginginPublication Data

Hardback ISBN: 9781119514602

Central Cover Image: Redrawn from by Hee Jeung Oh, with permission from The Electrochemical Society

Cover Image: Courtesy of John Newman, Nitash P. Balsara, and Hee Jeung Oh

Electrochemical systems provide the basis for many technologically important applications, such as batteries and fuel cells, production and refining of metals and chemicals, fabrication of electronic materials and devices, and operation of sensors, including those regulating the air/fuel ratio in automobile engines. The rechargeable lithiumion battery has emerged as a vital element of the emerging cleanenergy landscape. In biological systems, nerve action involves electrochemical processes. While applications continue to evolve, the fundamentals need only minor revision to train and guide people in adapting to new applications. Electrochemical systems involve many simultaneously interacting phenomena, drawn from many aspects of chemistry and physics, and require a disciplined learning process. The book provides a comprehensive coverage of electrochemical theories as they pertain to the understanding of electrochemical systems. It describes the foundations of thermodynamics, chemical kinetics, and transport phenomena including the electric potential and charged species.