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OHayre R. - Fuel Cell Fundamentals

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OHayre R. Fuel Cell Fundamentals

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3rd Edition. John Wiley & Sons, Inc., Hoboken, New Jersey, Canada, 2016. 830 p. ISBN: 1119113806Fuel Cell Fundamentals provides a thorough introduction to the principles and practicalities behind fuel cell technology. Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side with guidance on system types and design, performance, costs, and environmental impact. This new third edition has been updated with the latest technological advances and relevant calculations, and enhanced chapters on advanced fuel cell design and electrochemical and hydrogen energy systems. Worked problems, illustrations, and application examples throughout lend a real-world perspective, and end-of chapter review questions and mathematical problems reinforce the material learned.
Fuel cells produce more electricity than batteries or combustion engines, with far fewer emissions. This book is the essential introduction to the technology that makes this possible, and the physical processes behind this cost-saving and environmentally friendly energy source.
Understand the basic principles of fuel cell physics
Compare the applications, performance, and costs of different systems
Master the calculations associated with the latest fuel cell technology
Learn the considerations involved in system selection and design
As more and more nations turn to fuel cell commercialization amidst advancing technology and dropping deployment costs, global stationary fuel cell revenue is expected to grow from $1.4 billion to $40.0 billion by 2022. The sector is forecasted to explode, and there will be a tremendous demand for high-level qualified workers with advanced skills and knowledge of fuel cell technology. Fuel Cell Fundamentals is the essential first step toward joining the new energy revolution.
Table of Contents
Fuel Cell Principles
Introduction
Fuel Cell Thermodynamics
Fuel Cell Reaction Kinetics
Fuel Cell Charge Transport
Fuel Cell Mass Transport
Fuel Cell Modeling
Fuel Cell Characterization
Fuel Cell Technology
Overview of Fuel Cell Types
PEMFC and SOFC Materials
Overview of Fuel Cell Systems
Fuel Processing Subsystem Design
Thermal Management Subsystem Design
Fuel Cell System Design
Environmental Impact of Fuel Cells
Appendices
Constants and Conversions
Thermodynamic Data
Standard Electrode Potentials at 25C
Quantum Mechanics
Periodic Table of the Elements
Suggested Further Reading
Important Equations
Answers to Selected Chapter Exercises

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Table of Contents
Pages
Guide
List of Illustrations
  1. Chapter 1: Introduction
  2. Chapter 2: Fuel Cell Thermodynamics
  3. Chapter 3: Fuel Cell Reaction Kinetics
  4. Chapter 4: Fuel Cell Charge Transport
  5. Chapter 5: Fuel Cell Mass Transport
  6. Chapter 6: Fuel Cell Modeling
  7. Chapter 7: Fuel Cell Characterization
  8. Chapter 8: Overview of Fuel Cell Types
  9. Chapter 9: PEMFC and SOFC Materials
  10. Chapter 10: Overview of Fuel Cell Systems
  11. Chapter 11: Fuel Processing Subsystem Design
  12. Chapter 12: Thermal Management Subsystem Design
  13. Chapter 13: Fuel Cell System Design
  14. Chapter 14: Environmental Impact of Fuel Cells
List of Tables
  1. Chapter 1: Introduction
  2. Chapter 2: Fuel Cell Thermodynamics
  3. Chapter 3: Fuel Cell Reaction Kinetics
  4. Chapter 4: Fuel Cell Charge Transport
  5. Chapter 5: Fuel Cell Mass Transport
  6. Chapter 6: Fuel Cell Modeling
  7. Chapter 7: Fuel Cell Characterization
  8. Chapter 8: Overview of Fuel Cell Types
  9. Chapter 10: Overview of Fuel Cell Systems
  10. Chapter 11: Fuel Processing Subsystem Design
  11. Chapter 12: Thermal Management Subsystem Design
  12. Chapter 13: Fuel Cell System Design
  13. Chapter 14: Environmental Impact of Fuel Cells
FUEL CELL FUNDAMENTALS
Third Edition

RYAN O'HAYRE
Department of Metallurgical and Materials Engineering
Colorado School of Mines
[PhD, Materials Science and Engineering, Stanford University]

SUK-WON CHA
School of Mechanical and Aerospace Engineering
Seoul National University
[PhD, Mechanical Engineering, Stanford University]

WHITNEY G. COLELLA
The G.W.C. Whiting School of Engineering, and The Energy, Environment,
Sustainability and Health Institute
The Johns Hopkins University
Gaia Energy Research Institute
[Doctorate, Engineering Science, The University of Oxford]

FRITZ B. PRINZ
R.H. Adams Professor of Engineering
Departments of Mechanical Engineering and Material Science and Engineering
Stanford University

Fuel Cell Fundamentals - image 1

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Copyright 2016 by John Wiley & Sons, Inc. All rights reserved.

Published by John Wiley & Sons, Inc., Hoboken, New Jersey.

Published simultaneously in Canada.

No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 646-8600, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at www.wiley.com/go/permissions.

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Wiley publishes in a variety of print and electronic formats and by print-on-demand. Some material included with standard print versions of this book may not be included in e-books or in print-on-demand. If this book refers to media such as a CD or DVD that is not included in the version you purchased, you may download this material at http://booksupport.wiley.com. For more information about Wiley products, visit www.wiley.com.

Library of Congress Cataloging-in-Publication Data is available:

ISBN 9781119113805 (Cloth)

ISBN 9781119114208 (ePDF)

ISBN 9781119114154 (ePub)

Cover Design: Wiley

Cover Illustrations: Ryan O'Hayre

Cover Image: Glacial abstract shapes ppart/iStockphoto

To the parents who nurtured us.

To the teachers who inspired us.

Preface

Imagine driving home in a fuel cell car with nothing but pure water dripping from the tailpipe. Imagine a laptop computer that runs for 30 hours on a single charge. Imagine a world where air pollution emissions are a fraction of that from present-day automobiles and power plants. These dreams motivate today's fuel cell research. While some dreams (like cities chock-full of ultra-low-emission fuel cell cars) may be distant, others (like a 30-hour fuel cell laptop) may be closer than you think.

By taking fuel cells from the dream world to the real world, this book teaches you the science behind the technology. This book focuses on the questions how and why. Inside you will find straightforward descriptions of how fuel cells work, why they offer the potential for high efficiency, and how their unique advantages can best be used. Emphasis is placed on the fundamental scientific principles that govern fuel cell operation. These principles remain constant and universally applicable, regardless of fuel cell type or technology.

Following this philosophy, the first part, Fuel Cell Principles, is devoted to basic fuel cell physics. Illustrated diagrams, examples, text boxes, and homework questions are all designed to impart a unified, intuitive understanding of fuel cells. Of course, no treatment of fuel cells is complete without at least a brief discussion of the practical aspects of fuel cell technology. This is the aim of the second part of the book, Fuel Cell Technology. Informative diagrams, tables, and examples provide an engaging review of the major fuel cell technologies. In this half of the book, you will learn how to select the right fuel cell for a given application and how to design a complete system. Finally, you will learn how to assess the potential environmental impact of fuel cell technology.

Comments or questions? Suggestions for improving the book? Found a typo, think our explanations could be improved, want to make a suggestion about other important concepts to discuss, or have we got it all wrong? Please send us your feedback by emailing us at posts these discussions, fliers for the book, and additional educational materials. Thank you.

Acknowledgments

The authors would like to thank their friends and colleagues at Stanford University and the former Rapid Prototyping Laboratory (RPL), now the Nano-Prototyping Laboratory (NPL), for their support, critiques, comments, and enthusiasm. Without you, this text would not have been written! The beautiful figures and illustrations featured in this textbook were crafted primarily by Marily Mallison, with additional illustrations by Dr. Michael Sanderstheir artistic touch is greatly appreciated!

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