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Hren Christopher R. - Chemistry Workbook For Dummies

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Hren Christopher R. Chemistry Workbook For Dummies

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pt. II. Making and remaking compounds -- 5. Building bonds -- Pairing charges with ionic bonds -- Sharing electrons with covalent bonds -- Occupying and overlapping molecular orbitals -- Polarity : sharing electrons unevenly -- Shaping molecules : VSEPR theory and hybridization -- 6. Naming compounds and writing formulas -- Labeling ionic compounds and writing their formulas -- Getting a grip on ionic compounds with polyatomic ions -- Naming molecular (covalent) compounds and writing their formulas -- Addressing acids -- Mixing the rules for naming and formula writing -- Beyond the basics : naming organic carbon chains -- 7. Understanding the many uses of the mole -- The mole conversion factor : Avogadros number -- Doing mass and volume mole conversions -- Determining percent composition -- Calculating empirical formulas -- Using empirical formulas to find molecular formulas -- 8. Getting a grip on chemical equations -- Translating chemistry into equations and symbols -- Balancing chemical equations -- Recognizing reactions and predicting products -- Combination (synthesis) -- Decomposition -- Single replacement (single displacement) -- Combustion -- Canceling spectator ions : net ionic equations -- 9. Putting stoichiometry to work -- Using mole-mole conversions from balanced equations -- PUtting moles at the center : conversions involving particles, volumes, and masses -- Limiting your reagents -- Percent yield calculations --;pt. III. Examining changes in terms of energy -- 10. Understanding states in terms of energy -- Describing states of matter with the kinetic molecular theory -- Figuring out phase transitions and diagrams -- 11. Obeying gas laws -- Boyles Law : playing with pressure and volume -- Charless Law and absolute zero : looking at volume and temperature -- The combined and ideal gas laws : working with pressure, volume, and temperature -- Daltons Law of Partial Pressures -- Diffusing and effusing with Grahams Law -- 12. Dissolving into solutions -- Seeing different forces at work in solubility -- Concentrating on molarity and percent solutions -- Changing concentrations by making dilutions -- Altering solubility with temperature -- 13. Playing hot and cold : colligative properties -- Portioning particles : molality and mole fractions -- Elevating and calculating boiling points -- Depressing and calculating freezing points -- Determining molecular masses with boiling and freezing points -- 14. Exploring rates and equilibrium -- Measuring rates -- Focusing on factors that affect rates -- Measuring equilibrium -- The equilibrium constant -- Free energy -- 15. Warming up to thermochemistry -- Understanding the basics of thermodynamics -- working with specific heat capacity and calorimetry -- Absorbing and releasing heat : endothermic and exothermic reactions -- Summing heats with Hesss Law --;pt. IV. Swapping charges -- 16. Working with acids and bases -- Surveying three complementary methods for defining acids and bases -- Arrhenius sticks to the basics -- Brnsted-Lowry tackles bases without a hydroxide ion -- Lewis relies on electron pairs -- Measuring acidity and basicity : pH, pOH, and K(w )-- K(a) and K(b) : finding strength through dissociation -- 17. Achieving neutrality with titrations and buffers -- Concentrating on titration to figure out molarity -- Maintaining your pH with buffers -- Measuring salt solubility with K(sp) -- 18. Accounting for electrons in redox -- Oxidation numbers : keeping t abs on electrons -- Balancing redox reactions under acidic conditions -- Balancing redox reactions under basic conditions -- 19. Galvanizing yourself to do electrochemistry -- Identifying anodes and cathodes -- Calculating electromotive force and standard reduction potentials -- Coupling current to chemistry : electrolytic cells -- 20. Doing chemistry with atomic nuclei -- decaying nuclei in different ways -- Alpha decay -- Beta decay -- Gamma decay -- Measuring rates of decay : half-lives -- Making and breaking nuclei : fusion and fission --;Hundreds of practice problems to help you conquer chemistry. Are you confounded by chemistry? Subject by subject, problem by problem, Chemistry Workbook For Dummies lends a helping hand so you can make sense of this often-intimidating subject. Packed with hundreds of practice problems that cover the gamut of everything youll encounter in your introductory chemistry course, this hands-on guide will have you working your way through basic chemistry in no time. You can pick and choose the chapters and types of problems that challenge you the most, or you can work from cover to cover. With plenty of practice problems on everything from matter and molecules to moles and measurements, Chemistry Workbook For Dummieshas everything you need to score higher in chemistry.;pt. V. The part of tens -- 21. Ten chemistry formulas to tattoo to your brain -- 22. Ten annoying exceptions to chemistry rules.;pt. I. Getting cozy with numbers, atoms, and elements -- 1. Noting numbers scientifically -- Using exponential and scientific notation to report measurements -- Multiplying and dividing in scientific notation -- Using exponential notation to add and subtract -- distinguishing between accuracy and precision -- Expressing precision with significant figures-- doing arithmetic with significant figures -- 2. Using and converting units -- Familiarizing yourself with base units and metric system prefixes -- Building derived units from base units -- Converting between units : the conversion factor -- Letting the units guide you -- 3. Breaking down atoms -- The atom : protons, electrons, and neutrons -- Deciphering chemical symbols : atomic and mass numbers -- Accounting for isotopes using atomic masses -- 4. Surveying the Periodic Table of the Elements -- Organizing the Periodic Table into periods and groups -- Predicting properties from periodic and group trends -- Seeking stability with valence electrons by forming ions -- Putting electrons in t heir places : electron configurations -- Measuring the amount of energy (or light) an excited electron emits --

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Chemistry Workbook For Dummies 2nd Edition Published by John Wiley Sons - photo 1

Chemistry Workbook For Dummies, 2nd Edition

Published by: John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030-5774, www.wiley.com

Copyright 2015 by John Wiley & Sons, Inc., Hoboken, New Jersey

Published simultaneously in Canada

No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except as permitted under Sections 107 or 108 of the 1976 United States Copyright Act, without the prior written permission of the Publisher. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permissions .

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Library of Congress Control Number: 2014908772

ISBN 978-1-118-94004-4 (pbk); ISBN 978-1-118-94005-1 (ebk); ISBN 978-1-118-94006-8 (ebk)

Manufactured in the United States of America

10 9 8 7 6 5 4 3 2 1

About the Authors

Peter Mikulecky grew up in Milwaukee, an area of Wisconsin unique for its high human-to-cow ratio. After a breezy four-year tour in the Army, Peter earned a bachelor of science degree in biochemistry and molecular biology from the University of WisconsinEau Claire and a PhD in biological chemistry from Indiana University. With science seething in his DNA, he sought to infect others with a sense of molecular wonderment. Having taught, tutored, and mentored in classroom and laboratory environments, Peter was happy to find a home at Fusion Learning Center and Fusion Academy. There, he enjoys convincing students that biology and chemistry are, in fact, fascinating journeys, not entirely designed to inflict pain on hapless teenagers. His military training occasionally aids him in this effort.

Chris Hren is a high school chemistry teacher. He has been happily married for a while now and loves spending time with his family. Chris is a proud graduate of Michigan State University and spends every Saturday in the fall watching his Spartans. Chris has coached football and track and is a pretty big sports fan in general. His family is lucky enough to have a small cottage on a lake in Northern Michigan, where he enjoys many outdoor activities. Chris loves to read, especially science fiction books.

Dedication

Peter Mikulecky: I would like to dedicate this book to my family and friends who supported me during the writing process. Also, to all my students who motivate me to be a better teacher by pushing me to find unique and fresh ways to reach them.

Chris Hren: I would like to dedicate this book to my wife. Without her support, none of this would have been possible. I love her dearly.

Authors Acknowledgments

Peter Mikulecky: Thanks to Bill Gladstone from Waterside Productions for being an amazing agent and friend. Thanks to Georgette Beatty, our project editor, for her clear feedback and support. A special shout-out to our acquisitions editor, Lindsay Lefevere, who, for reasons unclear, seems to keep wanting to work with us.

Chris Hren: Thanks to my wife and family again. A special thanks goes out to Georgette Beatty and Danielle Voirol for being such wonderful editors. Thank you as well to my students.

Publishers Acknowledgments

Executive Editor: Lindsay Sandman Lefevere

Senior Project Editor: Georgette Beatty

Copy Editor: Danielle Voirol

Technical Editors: Jason Dunham, Patti Smykal

Project Coordinator: Emily Benford

Cover Image: iStock.com/Eraxion

Chapter 1

Noting Numbers Scientifically

In This Chapter

Picture 2 Crunching numbers in scientific and exponential notation

Picture 3 Telling the difference between accuracy and precision

Picture 4 Doing math with significant figures

Like any other kind of scientist, a chemist tests hypotheses by doing experiments. Better tests require more reliable measurements, and better measurements are those that have more accuracy and precision. This explains why chemists get so giggly and twitchy about high-tech instruments: Those instruments take better measurements!

How do chemists report their precious measurements? Whats the difference between accuracy and precision? And how do chemists do math with measurements? These questions may not keep you awake at night, but knowing the answers to them will keep you from making rookie mistakes in chemistry.

Using Exponential and Scientific Notation to Report Measurements

Because chemistry concerns itself with ridiculously tiny things like atoms and molecules, chemists often find themselves dealing with extraordinarily small or extraordinarily large numbers. Numbers describing the distance between two atoms joined by a bond, for example, run in the ten-billionths of a meter. Numbers describing how many water molecules populate a drop of water run into the trillions of trillions.

To make working with such extreme numbers easier, chemists turn to scientific notation, which is a special kind of exponential notation. Exponential notation simply means writing a number in a way that includes exponents. In scientific notation, every number is written as the product of two numbers, a coefficient and a power of 10. In plain old exponential notation, a coefficient can be any value of a number multiplied by a power with a base of 10 (such as 104). But scientists have rules for coefficients in scientific notation. In scientific notation, the coefficient is always at least 1 and always less than 10. For example, the coefficient could be 7, 3.48, or 6.0001.

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