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Peter A. Thrower - Chemistry and Physics of Carbon: A Series of Advances

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Volume 25 introduces methods for the preparation of carbyne and addresses theoretical issues; discusses carbyne properties, spectroscopy, and chemical and crystal structure; explains the use of x-ray and neutron scattering for the structural evaluation of carbonaceous materials; and more.

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title Chemistry and Physics of Carbon a Series of Advances Vol 25 - photo 1

title:Chemistry and Physics of Carbon : a Series of Advances. Vol. 25 Chemistry and Physics of Carbon ; V. 25
author:Thrower, Peter A.
publisher:CRC Press
isbn10 | asin:0824793684
print isbn13:9780824793685
ebook isbn13:9780585360201
language:English
subjectCarbon--Chemistry, Carbon compounds--Chemistry.
publication date:1997
lcc:QD181.C1C45 1997eb
ddc:546.681
subject:Carbon--Chemistry, Carbon compounds--Chemistry.
Page i
Chemistry and Physics of Carbon:
Volume 25
A Series of Advances
Edited by
Peter A. Thrower
Department of Materials Science and Engineering
The Pennsylvania State University
University Park, Pennsylvania
Page ii The Library of Congress Cataloged the First Issue of This Title as - photo 2
Page ii
The Library of Congress Cataloged the
First Issue of This Title as Follows:
Chemistry and physics of carbon, v. 1
London, E. Arnold; New York, M. Dekker, 1965-
v. illus. 24 cm
Editor: v. 1-P.L. Walker
1. Carbon. I. Walker, Philip L., ed.
QD181.C1C44 546.681
Library of Congress 1 66-58302
ISBN 0-8247-9368-4
The publisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketing at the address below.
This book is printed on acid-free paper.
Copyright 1997 by Marcel Dekker, Inc. All Rights Reserved.
Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfilming, and recording, or by any information storage and retrieval system, without permission in writing from the publisher.
Marcel Dekker, Inc.
270 Madison Avenue, New York, New York 10016
Current printing (last digit):
10 9 8 7 6 5 4 3 2 1
PRINTED IN THE UNITED STATES OF AMERICA
Page iii
Preface
One cannot help wondering whether prefaces to volumes such as these serve any useful purpose. In my opinion they should introduce the chapters contained in the volume and perhaps set the scene for any future developments in the series, which is what I have always tried to do. This preface is intended neither to give an analysis of recent important developments in carbon science nor to prophesy what will happen in the years ahead. It was therefore amusing to recently read that in the preface to Volume 23, after acknowledging the recent fascination with Buckminster-fullerene, I "went on to list work that could only seem mundane... like the mayor in a council meeting pausing briefly to acknowledge that a UFO has landed in the town square before returning to 'any other business'" (The Most Beautiful Molecule, H. Aldersey-Williams, Wiley, 1995). Not only did the writer fail to cite the correct publisher for this series, but he also missed the purpose of the preface. While the councillors would almost certainly have abandoned their meeting under the cited circumstances, scientists have long learned not to abandon their current work for the novelties that occasionally come along. Vide the tremendous interest in carbon intercalation compounds some years ago. In this volume we go about our business as usual with three quite different and interesting chapters on carbon materials.
Page iv
While we have never been able to obtain anything other than promises of chapters on fullerenes, which undoubtedly do exist, we have been able to obtain a chapter on a form of carbon that many believe to be fictitious or, at the least, very unstable. I speak of course, of the linear carbons known as carbynes. A colleague recently commented to me that he was relieved to read in a paper submitted for publication that such materials are "not stable on storage, even under argon." The first chapter in this volume, by Russian scientists who have long experience in the production of carbynes, therefore promises to be controversial. Whether there is any practical future for the use of carbynes in significant quantities remains to be seen.
The second chapter in this volume came about as a result of a discussion some years ago with a valued and much-missed colleague, Brian Kelly. Brian had been impressed with the writings of Dr. Hoinkis on the use of small-angle scattering phenomena, both x-ray and neutron, for the structural evaluation of carbonaceous materials and I therefore asked him if he would write this chapter. Ernst Hoinkis soon produced what I believe to be a state-of-the-art chapter on this subject, and I am sure it will prove to be an important reference for years to come.
The third and final chapter comes from two colleagues with whom it has been my privilege to have been associated for many years. Carbon has long been used as a catalyst support and as a catalyst in its own right, and it is these two aspects of its many interesting properties that are brought together in this fascinating contribution. The chapter provides an important introduction to the surface properties of carbonaceous materials and the ways in which these can be employed in a wide variety of important processes.
Once again we have a volume with contributions on a wide range of subjects provided by leading scientists from different parts of the world, in this case Russia, Germany, Spain, and the United States.
I cannot finish without pointing out that this is the silver jubilee edition of this series, which Phil Walker started just over thirty years ago. He asked me to join him as an editor beginning with volume 8 in 1973. When he retired I assumed total responsibility for the series, and now that we have reached this milestone I feel it is time for me to pass the responsibility to another colleague. It is with great pleasure, therefore, that I can announce that the publishers have agreed to Dr. Ljubisa Radovic's joining me as editor for Volume 26 and to his appointment as sole editor thereafter. I am convinced that Dr. Radovic's appointment will serve this series well in the future.
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