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Andrew J. Larkoski - Quantum Mechanics: A Mathematical Introduction

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Andrew J. Larkoski Quantum Mechanics: A Mathematical Introduction
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    Quantum Mechanics: A Mathematical Introduction
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This original and innovative textbook takes the unique perspective of introducing and solving problems in quantum mechanics using linear algebra methods, to equip readers with a deeper and more practical understanding of this fundamental pillar of contemporary physics. Extensive motivation for the properties of quantum mechanics, Hilbert space, and the Schrdinger equation is provided through analysis of the derivative, while standard topics like the harmonic oscillator, rotations, and the hydrogen atom are covered from within the context of operator methods. Advanced topics forming the basis of modern physics research are also included, such as the density matrix, entropy, and measures of entanglement. Written for an undergraduate audience, this book offers a unique and mathematically self-contained treatment of this hugely important topic. Students are guided gently through the text by the authors engaging writing style, with an extensive glossary provided for reference and numerous homework problems to expand and develop key concepts. Online resources for instructors include a fully worked solutions manual and lecture slides.

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Linear Algebra

Quantum mechanics is ultimately and fundamentally a framework for understanding Nature through the formalism of linear algebra, vector spaces, and the like. In principle, your study of linear algebra from an introductory mathematics course would be necessary and sufficient background for studying quantum mechanics, but such a course is typically firmly rooted in the study of matrices and their properties. This is definitely relevant for quantum mechanics, but we will need a more general approach to linear algebra to be able to describe the dynamics of interesting physical systems and make predictions. Perhaps the most familiar and important linear operator, the derivative, was not even discussed within that context in a course on linear algebra. Because of this familiarity, studying properties of the derivative is an excellent place to begin to dip our toes into the shallow waters of the formalism of quantum mechanics.

2.1 Invitation: The Derivative Operator

Lets first consider a function of one variable, Picture 1 . Here, Picture 2 is a position, for example, and Picture 3 might be the amplitude of a jiggled rope at position Picture 4 . Precisely what function Picture 5 is, is not relevant for our current discussion. We can draw an example function as illustrated in . On this plot, I have identified the point Picture 6 at which the function takes a value Picture 7 . Now, from Picture 8 , how do I move along in Picture 9 to get to a new point a distance Picture 10 to the right? The function value at this new point is, of course, Picture 11 . However, to get there from the point Picture 12 , that is, to establish the value Picture 13 exclusively from data at Picture 14 , we can use the Taylor expansion

Fig. 2.1

Representation of the action of displacement from point to point of a function 21 To move a distance - photo 15 to point of a function 21 To move a distance away from - photo 16 of a function 21 To move a distance away from I need to know all of - photo 17 .

21 To move a distance away from I need to know all of the derivatives of - photo 18 (2.1)

To move a distance Picture 19 away from Picture 20 , I need to know all of the derivatives of Picture 21 , evaluated at This seems very complicated and like we would actually need an infinite - photo 22 . This seems very complicated and like we would actually need an infinite amount of data to proceed.

However, lets re-write this Taylor expansion in the compact form

22 Further because the derivative is a linear operator we can write 23 - photo 23 (2.2)

Further, because the derivative is a linear operator, we can write

23 Now the sum in parentheses looks very familiar If we just think of the - photo 24 (2.3)

Now, the sum in parentheses looks very familiar. If we just think of the multiple derivative Quantum Mechanics A Mathematical Introduction - image 25 as the multiplication of Quantum Mechanics A Mathematical Introduction - image 26 with itself Quantum Mechanics A Mathematical Introduction - image 27 times, the sum has the form

Quantum Mechanics A Mathematical Introduction - image 28 (2.4)

which is just the exponential function! Using this generous interpretation for now, the sum over derivatives is then

25 So the Taylor expansion of the function can be represented as 26 - photo 29 (2.5)

So, the Taylor expansion of the function can be represented as 26 This awkward exponential of a derivative is - photo 30 can be represented as

26 This awkward exponential of a derivative is defined by its Taylor - photo 31 (2.6)

This awkward exponential of a derivative is defined by its Taylor expansion. In this construction, we exploited the linearity of the derivative as an operator that acts on functions. In this chapter, we will remind about the properties of linear operators and then use that to provide a profoundly new interpretation of the derivative that we will exploit.

2.2 Linearity

You are most likely familiar with the property of linearity from a course on linear algebra (the similarity of names is not a coincidence). For a matrix Quantum Mechanics A Mathematical Introduction - image 32 and vectors Quantum Mechanics A Mathematical Introduction - image 33 and Quantum Mechanics A Mathematical Introduction - image 34

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