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David J. Griffiths - Introduction to Quantum Mechanics

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David J. Griffiths Introduction to Quantum Mechanics

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Introduction to Quantum Mechanics

Third edition

Changes and additions to the new edition of this classic textbook include:

  • A new chapter on Symmetries and Conservation Laws
  • New problems and examples
  • Improved explanations
  • More numerical problems to be worked on a computer
  • New applications to solid state physics
  • Consolidated treatment of time-dependent potentials

David J. Griffiths received his BA (1964) and PhD (1970) from Harvard University. He taught at Hampshire College, Mount Holyoke College, and Trinity College before joining the faculty at Reed College in 1978. In 20012002 he was visiting Professor of Physics at the Five Colleges (UMass, Amherst, Mount Holyoke, Smith, and Hampshire), and in the spring of 2007 he taught Electrodynamics at Stanford. Although his PhD was in elementary particle theory, most of his research is in electrodynamics and quantum mechanics. He is the author of over fifty articles and four books: Introduction to Electrodynamics (4th edition, Cambridge University Press, 2013), Introduction to Elementary Particles (2nd edition, Wiley-VCH, 2008), Introduction to Quantum Mechanics (2nd edition, Cambridge, 2005), and Revolutions in Twentieth-Century Physics (Cambridge, 2013).

Darrell F. Schroeter is a condensed matter theorist. He received his BA (1995) from Reed College and his PhD (2002) from Stanford University where he was a National Science Foundation Graduate Research Fellow. Before joining the Reed College faculty in 2007, Schroeter taught at both Swarthmore College and Occidental College. His record of successful theoretical research with undergraduate students was recognized in 2011 when he was named as a KITP-Anacapa scholar.

INTRODUCTION TO Quantum Mechanics

Third edition

DAVID J. GRIFFITHS and DARRELL F. SCHROETER

Reed College, Oregon

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Cambridge University Press is part of the University of Cambridge.

It furthers the Universitys mission by disseminating knowledge in the pursuit of education, learning, and research at the highest international levels of excellence.

www.cambridge.org

Information on this title: www.cambridge.org/9781107189638

DOI: 10.1017/9781316995433

Second edition David Griffiths 2017

Third edition Cambridge University Press 2018

This publication is in copyright. Subject to statutory exception and to the provisions of relevant collective licensing agreements, no reproduction of any part may take place without the written permission of Cambridge University Press.

This book was previously published by Pearson Education, Inc. 2004

Second edition reissued by Cambridge University Press 2017

Third edition 2018

Printed in the United Kingdom by TJ International Ltd. Padstow Cornwall, 2018

A catalogue record for this publication is available from the British Library.

Library of Congress Cataloging-in-Publication Data

Names: Griffiths, David J. | Schroeter, Darrell F.

Title: Introduction to quantum mechanics / David J. Griffiths (Reed College, Oregon), Darrell F. Schroeter (Reed College, Oregon).

Description: Third edition. | blah : Cambridge University Press, 2018.

Identifiers: LCCN 2018009864 | ISBN 9781107189638

Subjects: LCSH: Quantum theory.

Classification: LCC QC174.12 .G75 2018 | DDC 530.12dc23

LC record available at https://lccn.loc.gov/2018009864

ISBN 978-1-107-18963-8 Hardback

Additional resources for this publication at www.cambridge.org/IQM3ed

Cambridge University Press has no responsibility for the persistence or accuracy of URLs for external or third-party internet websites referred to in this publication and does not guarantee that any content on such websites is, or will remain, accurate or appropriate.

Contents
Preface

Unlike Newtons mechanics, or Maxwells electrodynamics, or Einsteins relativity, quantum theory was not createdor even definitively packagedby one individual, and it retains to this day some of the scars of its exhilarating but traumatic youth. There is no general consensus as to what its fundamental principles are, how it should be taught, or what it really means. Every competent physicist can do quantum mechanics, but the stories we tell ourselves about what we are doing are as various as the tales of Scheherazade, and almost as implausible. Niels Bohr said, If you are not confused by quantum physics then you havent really understood it; Richard Feynman remarked, I think I can safely say that nobody understands quantum mechanics.

The purpose of this book is to teach you how to do quantum mechanics. Apart from some essential background in Chapter .

Not only is quantum theory conceptually rich, it is also technically difficult, and exact solutions to all but the most artificial textbook examples are few and far between. It is therefore essential to develop special techniques for attacking more realistic problems. Accordingly, this book is divided into two parts; .

This book is intended for a one-semester or one-year course at the junior or senior level. A one-semester course will have to concentrate mainly on Part . The reader must be familiar with the rudiments of linear algebra (as summarized in the Appendix), complex numbers, and calculus up through partial derivatives; some acquaintance with Fourier analysis and the Dirac delta function would help. Elementary classical mechanics is essential, of course, and a little electrodynamics would be useful in places. As always, the more physics and math you know the easier it will be, and the more you will get out of your study. But quantum mechanics is not something that flows smoothly and naturally from earlier theories. On the contrary, it represents an abrupt and revolutionary departure from classical ideas, calling forth a wholly new and radically counterintuitive way of thinking about the world. That, indeed, is what makes it such a fascinating subject.

At first glance, this book may strike you as forbiddingly mathematical. We encounter Legendre, Hermite, and Laguerre polynomials, spherical harmonics, Bessel, Neumann, and Hankel functions, Airy functions, and even the Riemann zeta functionnot to mention Fourier transforms, Hilbert spaces, hermitian operators, and ClebschGordan coefficients. Is all this baggage really necessary? Perhaps not, but physics is like carpentry: Using the right tool makes the job easier, not more difficult, and teaching quantum mechanics without the appropriate mathematical equipment is like having a tooth extracted with a pair of pliersits possible, but painful. (On the other hand, it can be tedious and diverting if the instructor feels obliged to give elaborate lessons on the proper use of each tool. Our instinct is to hand the students shovels and tell them to start digging. They may develop blisters at first, but we still think this is the most efficient and exciting way to learn.) At any rate, we can assure you that there is no

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